Search results for "chemistry [Arsenates]"

New evidence for the form and extent of the Pernicana Fault System (Mt. Etna) from structural and soil–gas surveying

1998

A multidisciplinary study based on structural and soil–gas surveys was carried out in order to investigate the relationship between soil CO2 degassing and the tectonic setting of the lower northeastern flank of Mt. Etna volcano. The results show that anomalous soil CO2 emissions occur mainly along faults trending WNW–ESE and also where these faults intersect the other main fault set (trending NE–SW) that displaces the study area. In particular, anomalies in CO2 degassing were revealed both along the Pernicana Fault and along another fault (Fiumefreddo Fault) which may represent the prolongation of the former towards the Ionian Sea coast. In the areas where these structures show evident surf…

Interaction between the deep fluids and the shallow groundwaters on Vulcano island (Italy)

2001

The aim of this work is to study the interactions processes between the fluids of deep origin and the shallow groundwaters of the Vulcano Porto area. During 1995, 13 well waters were sampled three times (May, July and November) and analysed for major and some minor elements (B, Br and NH4) and for dissolved gases. The close relationship of these waters with the deep magmatic source is highlighted by the composition of the dissolved gases. Furthermore, the areal distribution of dissolved species is controlled mainly by the gas fluxes from depth and by the presence of a deeper thermal aquifer. The distribution of major anomalies in the parameters measured in the groundwaters, in fact, overlap…

Accurate measurement of volcanic SO2flux: Determination of plume transport speed and integrated SO2concentration with a single device

2005

[1] Ground-based measurements of volcanic sulfur dioxide fluxes are important indicators of volcanic activity, with application in hazard assessment, and understanding the impacts of volcanic emissions upon the environment and climate. These data are obtained by making traverses underneath the volcanic plume a few kilometers from source with an ultraviolet spectrometer, measuring integrated SO2 concentrations across the plume's cross section, and multiplying by the plume's transport speed. However, plume velocities are usually derived from ground-based anemometers, located many kilometers from the traverse route and hundreds of meters below plume altitude, complicating the experimental desi…

Soil and fumarole gases of Mount Etna: geochemistry and relations with volcanic activity

1998

Abstract Between 1993 and 1996, gas samples were collected on Mt. Etna volcano from both high- and low-temperature fumaroles and from soils in areas of anomalous degassing located on the flanks of the volcanic edifice. The chemical composition of all the emitted gases is consistent with their magmatic origin. During their transport to the surface, they would undergo shallow mixing processes, mostly with air. Locally, as in the case of a point in the lower southwestern flank of the volcano (P39), very high contents of He and CH4 indicate that deep gases mainly interact with ground waters and also with a hydrocarbon reservoir. The isotopic composition of carbon in CO2 from these gases also su…

CO 2 output and δ 13 C(CO 2 ) from Mount Etna as indicators of degassing of shallow asthenosphere

1997

An estimated average CO2 output from Etna's summit craters in the range of 13±3 Mt/a has recently been determined from the measured SO2 output and measured CO2/SO2 molar ratios. To this amount the CO2 output emitted diffusely from the soil (≈ 1 Mt/a) and the amount of CO2 dissolved in Etna's aquifers (≈ 0.25 Mt/a) must be added. Data on the solubility of CO2 in Etnean magmas at high temperature and pressure allow the volume of magma involved in the release of such an amount of this gas to be estimated. This volume of magma (≈ 0.7 km3/a) is approximately 20 times greater than the volume of magma erupted annually during the period 1971–1995. On the basis of C-isotopic data of CO2 collected in…

2020

Abstract. New Zealand's Alpine Fault is a large, plate-bounding strike-slip fault, which ruptures in large (Mw>8) earthquakes. We conducted field and laboratory analyses of fault rocks to assess its fault zone architecture. Results reveal that the Alpine Fault Zone has a complex geometry, comprising an anastomosing network of multiple slip planes that have accommodated different amounts of displacement. This contrasts with the previous perception of the Alpine Fault Zone, which assumes a single principal slip zone accommodated all displacement. This interpretation is supported by results of drilling projects and geophysical investigations. Furthermore, observations presented here show th…

Eclogites within the Menderes Massif / western Turkey

1997

Metagabbros in the core series of the Menderes Massif, for some time considered as post orogenic Miocene intrusives, revealed a strong poly-metamorphic history. The metagabbro bodies exhibit a pronounced zonation. Within their cores, igneous minerals are still preserved. Coronitic textures are interpreted as results of a high temperature, possibly granulitic overprint. The outer parts of the metagabbro bodies mostly consist of strongly to completely retrograded gamet-amphibo-lites, but occasionally contain relies of eclogites. Petrologic investigations confirmed a high pressure overprint and allowed preliminary P, T estimates (650 degrees C, equal to or greater than 1.3 GPa). The intensity …

Recycling and transport of continental material through the mantle wedge above subduction zones: A Caribbean example

2016

Abstract Estimates of global growth rates of continental crust critically depend upon knowledge of the rate at which crustal material is delivered back into the mantle at subduction zones and is then returned to the crust as a component of mantle-derived magma. Quantification of crustal recycling by subduction-related magmatism relies on indirect chemical and isotopic tracers and is hindered by the large range of potential melt sources (e.g., subducted oceanic crust and overlying chemical and clastic sediment, sub-arc lithospheric mantle, arc crust), whose composition may not be accurately known. There is also uncertainty about how crustal material is transferred from subducted lithosphere …

Long-time variation of soil CO2 fluxes at the summit crater of Vulcano (Italy)

2012

Here, we report the first continuous data of geochemical parameters acquired directly from the active summit crater of Vulcano. This approach provides a means to better investigate deep geochemical processes associated with the degassing system of Vulcano Island. In particular, we report on soil CO2 fluxes from the upper part of Vulcano, a closed-conduit volcano, from September 2007 to October 2010. Large variations in the soil CO2 and plume SO2 fluxes (order of magnitude), coinciding with other discontinuous geochemical parameters (CO2 concentrations in fumarole gas) and physical parameters (increase of shallow seismic activity and fumarole temperatures) have been recorded. The results fro…

Volcanic CO2 flux measurement at Campi Flegrei by tunable diode laser absorption spectroscopy

2014

Near-infrared room-temperature Tunable Diode Lasers (TDL) have recently found increased usage in atmospheric chemistry and air monitoring research, but applications in volcanology are still limited to a few examples. Here, we explored the potential of a commercial infrared laser unit (GasFinder 2.0 from Boreal Laser Ltd) for measurement of volcanic CO2 mixing ratios, and ultimately for estimating the volcanic CO2 flux. Our field tests were conducted at Campi Flegrei near Pozzuoli, Southern Italy, where the GasFinder was used during three campaigns in October 2012, January 2013 and May 2013 to repeatedly measure the path-integrated mixing ratios of CO2 along cross-sections of the atmospheric…